Preheat the oven to 350ºF, and line an 8×8-inch baking dish with parchment paper. Spray with nonstick cooking spray; set aside.
In a medium saucepan, melt the butter over medium-low heat. As the butter melts, it’ll start to foam, then turn a clear golden color. Continue to stir the butter, scraping up any browned specks from the bottom of the pan as it starts to brown. It should have a nutty aroma.
Once browned and nutty, turn off the heat and allow to cool for 5 minutes.
Whisk in both sugars, the egg, and vanilla until smooth. Switch to a wooden spoon, add the flour, baking powder, and salt and stir until just combined. Try not to overmix.
Turn batter out into prepared pan, spreading batter evenly with a rubber spatula. Bake for about 20-23 minutes, or until edges are firm and golden and the center jiggles slightly; do not overbake. Blondies firm up as they cool.