Preheat the oven to 350ºF, and line a baking sheet with parchment paper.
In a medium bowl, whisk the flour, cocoa powder, baking soda a salt together until combined; set aside.
In a small bowl, combine the instant espresso powder and hot water until completely dissolved; set aside.
Cream the butter, brown sugar, and granulated sugar together until smooth and creamy. Add the egg, egg yolk, vanilla, and espresso mixture, and mix until completely incorporated. Add the dry ingredients, mixing until just combined.
Shape dough into balls, and place them onto the prepared baking sheet. Gently flatten each ball to about ½ inch in thickness (see photo above). Bake in the preheated oven for 8-10 minutes. Allow the cookies to cool on the baking sheet for 10 minutes before transferring to a cooling rack.